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Title: Development of chiral nitrogen ligands for application in homogeneous catalysis
Authors: Fanfoni, Lidia
Keywords: asymmetric catalysischemoenzymatic synthesischiral pincer ligandsbipyridine ligandshybrid phosphorous-nitrogen ligands
Issue Date: 26-Mar-2010
Publisher: Università degli studi di Trieste
Abstract: Aim of this thesis is the synthesis of enantiomerically pure ligands for their application in asymmetric catalysis. In particular, the work is focused on the synthesis of three different classes of ligands. Chapters 2 and 3 deal with the synthesis of CNN-pincer and N-Nˈ(bipyridine) ligands respectively, obtained in both enantiomeric forms by stereocomplementary chemoenzymatic methods, while Chapter 4 presents the synthesis of P-N type ligands obtained from L-proline. The activity of the complexes that containing the optically pure synthesized ligands was also investigated.
Description: 2008/2009
NBN: urn:nbn:it:units-8869
Appears in Collections:Scienze chimiche

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